I had no idea this show exists, but I came across a reference to it on Basket of Kisses, the big Mad Men site. Pollak just had Michael Gladis and Rich Sommer on.
Pollak is a very good interviewer, which for some reason surprises me a bit. He basically plays it straight, but throws in jokey stuff every now and then, so it's a very satisfying mix. It helps that he seems genuinely curious about the people he's interviewing, plus he's just very comfortable in front of a camera.